%0 Journal Article %@holdercode {isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S} %@nexthigherunit 8JMKD3MGPCW/3ET2RFS %@resumeid 8JMKD3MGP5W/3C9JHSB %@resumeid %@resumeid 8JMKD3MGP5W/3C9JGJ8 %@resumeid 8JMKD3MGP5W/3C9JHU5 %@archivingpolicy denypublisher denyfinaldraft24 %@usergroup administrator %@usergroup sergio %3 surface polyethylene.pdf %@dissemination WEBSCI; PORTALCAPES. %X Plasma immersion ion implantation (PIII) of nitrogen has been successfully employed to form an amorphous carbon layer on the surface of 0.25-mm-thick polyethylene terephthalate (PET) sheet used for manufacturing plastic bottles. A DC glow discharge source with controlled floating plasma potential was used to create nitrogen plasma in a 100-1 PIII system. The polymer specimens were pulsed (through a metallic grid or sample holder) at repetition rate of 300 Hz with high negative voltage pulse of 10 W magnitude and 80 mus duration. Formation of carbon film on the PET surface as a result of nitrogen ion implantation was investigated using Raman spectroscopy, optical and atomic force microscopy (AFM). The obtained Raman spectra reveal that the amorphous carbon layer has diamond-like characteristics. AFM micrographs demonstrate that after PIII treatment, the PET surface became much smoother and no cracks were found on it. (C) 2004 Elsevier B.V. All rights reserved. %8 aug. %N 1-2 %T Surface modification of polyethylene terephthalate by plasma immersion ion implantation %K plasma immersion ion implantation, PET, diamond-like carbon, RAMAN DIAMOND-LIKE CARBON, PET FILM, AMORPHOUS-CARBON, DEPOSITION. %@secondarytype PRE PI %@group LAP-INPE-MCT-BR %@copyholder SID/SCD %@secondarykey INPE-11790-PRE/7149 %@issn 0257-8972 %2 sid.inpe.br/marciana/2004/12.09.10.25.12 %@affiliation Ueda M (reprint author), INPE, Natl Inst Space Res, Associated Plasma Lab, POB 515, Sao Jose Dos Campos, SP BR-12201970 Brazil, %@affiliation INPE, Natl Inst Space Res, Associated Plasma Lab, Sao Jose Dos Campos, SP BR-12201970 Brazil, %@affiliation Univ Sofia, Dept Gen Phys, Sofia, 1164 Bulgaria, %@affiliation INPE, Associated Lab Mat & Sensors, Sao Jose Dos Campos, SP BR-12201970 Brazil, %@affiliation Bulgarian Acad Sci, Inst Elect, Sofia, BU-1784 Bulgaria, %B Surface and Coatings Technology %@language English %P 295-298 %4 sid.inpe.br/marciana/2004/12.09.10.25 %D 2004 %V 186 %A Ueda, Mario, %A Kostov, K. G., %A Beloto, Antonio Fernando, %A Leite, Nelia Ferreira, %A Grigorov, K. G., %@area FISMAT